Synopsis
This thesis is based on the excellent radical scavenging properties of mono meric nitrosoalkanes RNO. Thus, addition of a small amount of RNO to a reacting system in which unstable radicals X· are generated usually results in the formation of relatively stable nitroxides, which can be studied by ESR spectroscopy at room temperature . . R-N=O + X --R-N-X ,. o The nature of the trapped radical X· can very often be deduced from the hyperfine splittings (hfs) and g-value of the ESR spectrum of the derived nitroxide. Thus the ESR Spin Trapping technique is useful for the identifi cation of highly reactive (short-living) radicals X·. Chapter 1 contains a survey of the literature and a short description of the most important features of nitrosoalkanes, nitroxides and the Spin Trapping technique in general. In chapter 2 the synthesis of hitherto unknown I-nitrosoadamantane is described. Together with a number of other nitrosoalkanes it is used as a scavenger for trifluoromethyl radicals, generated by photolysis of trifluoro iodomethane. The derived alkyl trifluoromethyl nitroxides with aN = aF = 11.5-12.0 gauss are easily identified and are found to be very stable at room temperature. Chapter 3 illustrates the limitations of the Spin Trapping technique, i.e.
"synopsis" may belong to another edition of this title.
Search results for Spin trapping by nitrosoalkanes: Mechanisms of Some...
Stock Image
Spin trapping by nitrosoalkanes: Mechanisms of Some Photochemically Induced Reactions
Seller: Lucky's Textbooks, Dallas, TX, U.S.A.
Seller rating 5 out of 5 stars
Condition: New. Seller Inventory # ABLIING23Apr0412070059162
Stock Image
Spin trapping by nitrosoalkanes: Mechanisms of Some Photochemically Induced Reactions
Seller: Ria Christie Collections, Uxbridge, United Kingdom
Seller rating 5 out of 5 stars
Condition: New. In. Seller Inventory # ria9789401186506_new
Buy New
£ 49.52
Shipping:
£ 11.98
From United Kingdom to U.S.A.
Quantity: Over 20 available
Stock Image
Spin trapping by nitrosoalkanes
Seller: Chiron Media, Wallingford, United Kingdom
Seller rating 4 out of 5 stars
Paperback. Condition: New. Seller Inventory # 6666-IUK-9789401186506
Buy New
£ 47.21
Shipping:
£ 15.49
From United Kingdom to U.S.A.
Quantity: 10 available
Stock Image
Spin trapping by nitrosoalkanes
Seller: Books Puddle, New York, NY, U.S.A.
Seller rating 4 out of 5 stars
Condition: New. pp. 68. Seller Inventory # 26357314928
Stock Image
Spin trapping by nitrosoalkanes: Mechanisms of Some Photochemically Induced Reactions
Seller: Revaluation Books, Exeter, United Kingdom
Seller rating 5 out of 5 stars
Paperback. Condition: Brand New. 1971 edition. 68 pages. 9.25x6.10x0.16 inches. In Stock. Seller Inventory # x-9401186502
Stock Image
Spin trapping by nitrosoalkanes
Print on DemandSeller: Majestic Books, Hounslow, United Kingdom
Seller rating 4 out of 5 stars
Condition: New. Print on Demand pp. 68 49:B&W 6.14 x 9.21 in or 234 x 156 mm (Royal 8vo) Perfect Bound on White w/Gloss Lam. Seller Inventory # 356224687
Stock Image
Spin trapping by nitrosoalkanes
Print on DemandSeller: Biblios, Frankfurt am main, HESSE, Germany
Seller rating 4 out of 5 stars
Condition: New. PRINT ON DEMAND pp. 68. Seller Inventory # 18357314938
Seller Image
Spin trapping by nitrosoalkanes
Print on DemandSeller: moluna, Greven, Germany
Seller rating 4 out of 5 stars
Condition: New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. 1. Introduction and Survey of Literature.- Nitrosoalkanes.- Nitroxides.- ESR Spin Trapping techniques.- 2. Trapping of Trifluoromethyl Radicals by Monomeric Nitrosoalkanes. Synthesis of 1-Nitrosoadamantane.- Results and discussion.- Experimental.- 3. Photol. Seller Inventory # 5836362
Seller Image
Spin trapping by nitrosoalkanes
Published by
Springer Netherlands Jan 1971, 1971
ISBN 10: 9401186502
ISBN 13: 9789401186506
New
Taschenbuch
Seller: BuchWeltWeit Ludwig Meier e.K., Bergisch Gladbach, Germany
Seller rating 5 out of 5 stars
Taschenbuch. Condition: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -This thesis is based on the excellent radical scavenging properties of mono meric nitrosoalkanes RNO. Thus, addition of a small amount of RNO to a reacting system in which unstable radicals X are generated usually results in the formation of relatively stable nitroxides, which can be studied by ESR spectroscopy at room temperature . . R-N=O + X --R-N-X , o The nature of the trapped radical X can very often be deduced from the hyperfine splittings (hfs) and g-value of the ESR spectrum of the derived nitroxide. Thus the ESR Spin Trapping technique is useful for the identifi cation of highly reactive (short-living) radicals X . Chapter 1 contains a survey of the literature and a short description of the most important features of nitrosoalkanes, nitroxides and the Spin Trapping technique in general. In chapter 2 the synthesis of hitherto unknown I-nitrosoadamantane is described. Together with a number of other nitrosoalkanes it is used as a scavenger for trifluoromethyl radicals, generated by photolysis of trifluoro iodomethane. The derived alkyl trifluoromethyl nitroxides with aN = aF = 11.5-12.0 gauss are easily identified and are found to be very stable at room temperature. Chapter 3 illustrates the limitations of the Spin Trapping technique, i.e. 68 pp. Englisch. Seller Inventory # 9789401186506
Seller Image
Spin trapping by nitrosoalkanes
Published by
Springer Netherlands, Springer Netherlands Jan 1971, 1971
ISBN 10: 9401186502
ISBN 13: 9789401186506
New
Taschenbuch
Seller: buchversandmimpf2000, Emtmannsberg, BAYE, Germany
Seller rating 5 out of 5 stars
Taschenbuch. Condition: Neu. This item is printed on demand - Print on Demand Titel. Neuware -This thesis is based on the excellent radical scavenging properties of mono meric nitrosoalkanes RNO. Thus, addition of a small amount of RNO to a reacting system in which unstable radicals X are generated usually results in the formation of relatively stable nitroxides, which can be studied by ESR spectroscopy at room temperature . . R-N=O + X --R-N-X , o The nature of the trapped radical X can very often be deduced from the hyperfine splittings (hfs) and g-value of the ESR spectrum of the derived nitroxide. Thus the ESR Spin Trapping technique is useful for the identifi cation of highly reactive (short-living) radicals X . Chapter 1 contains a survey of the literature and a short description of the most important features of nitrosoalkanes, nitroxides and the Spin Trapping technique in general. In chapter 2 the synthesis of hitherto unknown I-nitrosoadamantane is described. Together with a number of other nitrosoalkanes it is used as a scavenger for trifluoromethyl radicals, generated by photolysis of trifluoro iodomethane. The derived alkyl trifluoromethyl nitroxides with aN = aF = 11.5-12.0 gauss are easily identified and are found to be very stable at room temperature. Chapter 3 illustrates the limitations of the Spin Trapping technique, i.e.Springer Verlag GmbH, Tiergartenstr. 17, 69121 Heidelberg 68 pp. Englisch. Seller Inventory # 9789401186506