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Published by John Wiley & Sons Inc, New York, 2003
ISBN 10: 047198731X ISBN 13: 9780471987314
Language: English
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Hardcover. Condition: new. Hardcover. As in the study of transition metal complexes in solution, molecular spectroscopic methods - principally the infrared, ultraviolet/visible and electron spin resonance spectroscopies - have played key roles in establishing the concepts of coordination chemistry occurring at the surfaces of solids. This book describes the development of the principals of coordination chemistry of oxide surfaces using analyses of data obtained by these methods. The nature, properties, concentration of the surface adsorption centers and their influence on the character of interaction with different molecules are investigated. The book commences with an account of the basic theoretical principles and experimental techniques of the various spectroscopy methods, with special attention devoted to in situ measurements where the oxide or catalyst sample is in contact with the adsorbate or the reactant. A detailed account is presented of the methods for characterizing the oxidation state and degree of coordination of surface cations and oxygen anions by the adsorption of probe molecules. The complexation of many inorganic, organometallic and organic molecules with different oxide systems is critically examined, and a classification of formed surface compounds, based on the interaction with definite type of adsorption centers, is given. Possible mechanisms of numerous catalytic reactions, including the transformation of organic molecules over acidic catalysts via the carboionic mechanism, are discussed using the spectroscopic identifications of reaction intermediates. A comprehensive analysis of the literature on the interpretation of the spectra of surface compounds on oxides is presented. This highly illustrated and extensively referenced volume is intended for specialists working in the fields of surface physical chemistry, surface and materials sciences, and adsorption phenomena and is essential reading for those involved in the heterogeneous catalysis by transition metal-oxides. As in the study of transition metal complexes in solution, molecular spectroscopic methods -- principally the infrared, ultraviolet/visible and electron spin resonance spectroscopies -- have played key roles in establishing the concepts of coordination chemistry occurring at the surfaces of solids. Shipping may be from our UK warehouse or from our Australian or US warehouses, depending on stock availability.
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ISBN 10: 047198731X ISBN 13: 9780471987314
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Add to basketHardcover. Condition: new. Hardcover. As in the study of transition metal complexes in solution, molecular spectroscopic methods - principally the infrared, ultraviolet/visible and electron spin resonance spectroscopies - have played key roles in establishing the concepts of coordination chemistry occurring at the surfaces of solids. This book describes the development of the principals of coordination chemistry of oxide surfaces using analyses of data obtained by these methods. The nature, properties, concentration of the surface adsorption centers and their influence on the character of interaction with different molecules are investigated. The book commences with an account of the basic theoretical principles and experimental techniques of the various spectroscopy methods, with special attention devoted to in situ measurements where the oxide or catalyst sample is in contact with the adsorbate or the reactant. A detailed account is presented of the methods for characterizing the oxidation state and degree of coordination of surface cations and oxygen anions by the adsorption of probe molecules. The complexation of many inorganic, organometallic and organic molecules with different oxide systems is critically examined, and a classification of formed surface compounds, based on the interaction with definite type of adsorption centers, is given. Possible mechanisms of numerous catalytic reactions, including the transformation of organic molecules over acidic catalysts via the carboionic mechanism, are discussed using the spectroscopic identifications of reaction intermediates. A comprehensive analysis of the literature on the interpretation of the spectra of surface compounds on oxides is presented. This highly illustrated and extensively referenced volume is intended for specialists working in the fields of surface physical chemistry, surface and materials sciences, and adsorption phenomena and is essential reading for those involved in the heterogeneous catalysis by transition metal-oxides. As in the study of transition metal complexes in solution, molecular spectroscopic methods -- principally the infrared, ultraviolet/visible and electron spin resonance spectroscopies -- have played key roles in establishing the concepts of coordination chemistry occurring at the surfaces of solids. Shipping may be from multiple locations in the US or from the UK, depending on stock availability.
Published by John Wiley & Sons Inc, 2003
ISBN 10: 047198731X ISBN 13: 9780471987314
Language: English
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Add to basketCondition: New. As in the study of transition metal complexes in solution, molecular spectroscopic methods -- principally the infrared, ultraviolet/visible and electron spin resonance spectroscopies -- have played key roles in establishing the concepts of coordination chemistry occurring at the surfaces of solids. Num Pages: 690 pages, Illustrations. BIC Classification: PNFS; PNRX. Category: (P) Professional & Vocational. Dimension: 261 x 180 x 44. Weight in Grams: 1396. . 2003. Hardcover. . . . .
Published by John Wiley & Sons Inc, 2003
ISBN 10: 047198731X ISBN 13: 9780471987314
Language: English
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Published by John Wiley & Sons Inc, New York, 2003
ISBN 10: 047198731X ISBN 13: 9780471987314
Language: English
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Add to basketHardcover. Condition: new. Hardcover. As in the study of transition metal complexes in solution, molecular spectroscopic methods - principally the infrared, ultraviolet/visible and electron spin resonance spectroscopies - have played key roles in establishing the concepts of coordination chemistry occurring at the surfaces of solids. This book describes the development of the principals of coordination chemistry of oxide surfaces using analyses of data obtained by these methods. The nature, properties, concentration of the surface adsorption centers and their influence on the character of interaction with different molecules are investigated. The book commences with an account of the basic theoretical principles and experimental techniques of the various spectroscopy methods, with special attention devoted to in situ measurements where the oxide or catalyst sample is in contact with the adsorbate or the reactant. A detailed account is presented of the methods for characterizing the oxidation state and degree of coordination of surface cations and oxygen anions by the adsorption of probe molecules. The complexation of many inorganic, organometallic and organic molecules with different oxide systems is critically examined, and a classification of formed surface compounds, based on the interaction with definite type of adsorption centers, is given. Possible mechanisms of numerous catalytic reactions, including the transformation of organic molecules over acidic catalysts via the carboionic mechanism, are discussed using the spectroscopic identifications of reaction intermediates. A comprehensive analysis of the literature on the interpretation of the spectra of surface compounds on oxides is presented. This highly illustrated and extensively referenced volume is intended for specialists working in the fields of surface physical chemistry, surface and materials sciences, and adsorption phenomena and is essential reading for those involved in the heterogeneous catalysis by transition metal-oxides. As in the study of transition metal complexes in solution, molecular spectroscopic methods -- principally the infrared, ultraviolet/visible and electron spin resonance spectroscopies -- have played key roles in establishing the concepts of coordination chemistry occurring at the surfaces of solids. Shipping may be from our Sydney, NSW warehouse or from our UK or US warehouse, depending on stock availability.
Published by John Wiley & Sons Inc, 2003
ISBN 10: 047198731X ISBN 13: 9780471987314
Language: English
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Add to basketCondition: New. As in the study of transition metal complexes in solution, molecular spectroscopic methods -- principally the infrared, ultraviolet/visible and electron spin resonance spectroscopies -- have played key roles in establishing the concepts of coordination chemistry occurring at the surfaces of solids. Num Pages: 690 pages, Illustrations. BIC Classification: PNFS; PNRX. Category: (P) Professional & Vocational. Dimension: 261 x 180 x 44. Weight in Grams: 1396. . 2003. Hardcover. . . . . Books ship from the US and Ireland.