The Synergy Between Dynamics and Reactivity at Clusters and Surfaces

Language: English

Published by Springer, Springer Okt 2012, 2012

9401040605 / 9789401040600

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This item is printed on demand - Print on Demand Titel. Neuware -The analogy between the chemistry of molecular transition metal clusters and the processes of chemisorption and catalysis at metal surfaces (the Cluster Surface analogy) has for a number of years provided an interplay between experimental and theoretical inorganic and physical chemists. This collaborative approach has born fruit in the use of well defined modes of metal-ligand bonding in discrete molecular clusters, models for metal-ligand binding on surfaces. Some of the key topics discussed in The Synergy between Dynamics and Reactivity at Clusters and Surfaces are: (1) Mechanisms of the fluxional behaviour in clusters in the liquid phase and the connections with diffusion processes on extended surfaces. The role of metal-metal bond breaking in diffusion. (2) Analogies in the structure of chemisorbed species and related ligands on metallic clusters. (3) Analogies between benzene surface chemistry on extended metal surfaces and on metal surfaces in molecular cluster compounds with particular reference to structural distortions. (4) The role of mobile precursors for dissociation of chemisorption on extended metals and on clusters. Are there analogies in the ligand attachment during cluster compound synthesis (5) The role of defect sites on metal surfaces in catalyzing chemical reactions and the connection to the special bonding properties of sites on metal clusters having lowest metal-metal coordination. (6) The size of metal clusters needed to mimic surface phenomena on bulk metal surfaces. Different sites needed for different phenomena.Springer-Verlag KG, Sachsenplatz 4-6, 1201 Wien 380 pp. Englisch.…

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Title
The Synergy Between Dynamics and Reactivity at Clusters and Surfaces
Author
L. J. Farrugia
Publisher
Springer, Springer Okt 2012
Publication year
2012
Condition
Neu
Binding
Taschenbuch
Language
English
ISBN 10
9401040605
ISBN 13
9789401040600
Item weight
606 grams
Dimensions
240x160x21 mm

buchversandmimpf2000

Emtmannsberg, BAYE, Germany

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