Study On Metalloporphyrins

Language: English

Published by Scholars' Press Jun 2014, 2014

3639716507 / 9783639716504

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This item is printed on demand - Print on Demand Titel. Neuware -The work presented in the Book entitled 'Study on Metalloporphyrins' can be summarized in analytical and physical data; spectral data are compatible with the suggested structures. The complexes are colored, stable in air and insoluble in H2O, ethanol and non-polar solvents such as benzene. However, they dissolve in polar solvents such as DMF and DMSO. IR spectra of the complexes were recorded to confirm their structures. The assignments of the characteristic vibrational frequencies of the complexes were made by comparison with the vibrational frequencies of the free ligand. The ligand behaved as neutral tetradentate ligand coordinating through the four imine nitrogens. In all Complexes the signals of the imine groups were merged together and shifted to lower wave number accompanied by a decrease in their intensities, indicating they are involved in complex formation. The UV-Vis absorption spectrum of the complexes shows single d-d transition band in the 554-545 nm range as expected for a square planar copper(II) environment with similar N4 donor tetradentate Schiff base. 1H NMR studies of porphyrin reveal the aromatic nature of the porphyrin macrocycle.VDM Verlag, Dudweiler Landstraße 99, 66123 Saarbrücken 60 pp. Englisch.

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Title
Study On Metalloporphyrins
Author
Rakesh Tada
Publisher
Scholars' Press Jun 2014
Publication year
2014
Condition
Neu
Binding
Taschenbuch
Language
English
ISBN 10
3639716507
ISBN 13
9783639716504
Item weight
107 grams
Dimensions
220x150x5 mm

buchversandmimpf2000

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