The Spectroscopy of Flames

Language: English

Published by Springer, Springer Nov 2013, 2013

940095722X / 9789400957220

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This item is printed on demand - Print on Demand Titel. Neuware -I. Flame Spectra.- The purpose of studying flame spectra.- Types of spectra.- The structure of flames.- The spectrum of the Bunsen flame.- Equilibria, radiation and collision processes.- II. Experimental Methods.- The recording of spectra.- Spectrographic equipment.- Optical systems.- The study of absorption spectra.- Wavelength determination.- Intensity measurements.- Effects of flame shape.- III. Special Techniques.- Flat flames.- Low-pressure flames.- Temperature effects on flames.- Atomic flames.- Flash photolysis.- Shock tube studies.- Fluorescence and laser-Raman scattering.- Use of isotope shifts.- IV. Introduction to the Theory of Spectra.- Line or atomic spectra.- Bohr theory.- The spectra of diatomic molecules: vibrational structure.- Rotational structure of the spectra of diatomic molecules.- Electronic states of diatomic molecules.- Vibrational intensity distribution: the Franck.- Condon principle.- Predissociation.- Infra-red spectra.- Raman spectra.- Electronic spectra of polyatomic molecules.- Continuous spectra.- Ionization continua.- Dissociation continua.- Association continua.- The width and shape of spectrum lines.- V. Hydrogen Flames.- The OH bands.- Hydrogen/air flames.- Hydrogen/ oxygen flames.- Pressure effects.- Absorption spectra.- Excitation of metal spectra in H2/O2/N2 flames.- Candoluminescence.- Applications to combustion mechanism.- The hydrogen/nitrous oxide flame.- Flames with NO and NO2.- VI. The Carbon Monoxide Flame.- The spectrum.- The carbon monoxide flame bands.- The excitation of the flame bands.- The continuous spectrum: pressure and temperature effects.- Combustion processes for carbon monoxide.- Flames of carbon and carbon suboxide.- VII. The Spectra of Organic Flames.- The CH bands.- Bands of C2.- Vaidya's hydrocarbon flamebands (HCO).- The 4050 Å 'comet head' group (C3).- Emeléus's cool flame bands (CH2O).- Band systems of CO.- Other band systems in flames.- The carbon line, 2478.- Premixed flames.- Diffusion flames.- Cool flames and preignition glows.- Absorption spectra.- VIII. Measurements of Effective Temperature and Studies with Special Sources.- Electronic excitation temperatures.- Translational temperatures from Doppler broadening.- Measurement of rotational temperatures: OH.- Rotational temperatures for CH, C2, NH etc.- Effective vibrational temperatures.- Predissociation.- Flash photolysis.- Atomic flames.- Spectra excited by shock waves.- Occurrence of C2 and CH in some special flames.- Isotope tracer experiments.- IX. The Infra-Red Region.- The amount of radiation from flames.- Infra-red spectra of organic flames.- Relative band intensities and temperature measurements.- Radiation from explosion flames.- Cool flames.- Flames with nitrous oxide.- Flames with halogens.- X. Flame Structure and Reaction Processes.- Reactions in cool flames.- The formaldehyde excitation process.- Reactions in diffusion flames.- Reactions in premixed flames.- Carbon formation in premixed flames.- Concentrations of free radicals.- Reactions forming excited species.- Ionization and electron temperatures.- The high electronic excitation in the flame front.- Effects on flame structure of lags in equipartition of energy.- XI. Explosions, Engines and Industrial Flames.- Explosions in closed vessels.- Detonations.- The internal combustion engine: flame fronts and afterburning.- Knock.- Compression-ignition (diesel) engines.- Engines with continuous combustion.- Exhaust flames.- Furnace flames.- Solid propellants.- XII. Flames Containing Nitrogen, Halogens, Sulphur and Inorganic Substances.-Flames of ammonia, hydrazine etc.- Flames of organic nitrogen compounds.- Flames supported by oxides of nitrogen.- Formation of oxides of nitrogen.- Ozone.- Halogens in oxidizing flames.- Flames supported by halogens.- Flames of sulphur, hydrogen sulphide and carbon disulphide.- Flames with added SO2, SO3 or H2S.- Phosphorus in flames.- Flames containi. …

Seller Inventory # 9789400957220

Title
The Spectroscopy of Flames
Author
A. Gaydon
Publisher
Springer, Springer Nov 2013
Publication year
2013
Condition
Neu
Binding
Taschenbuch
Language
English
ISBN 10
940095722X
ISBN 13
9789400957220
Item weight
668 grams
Dimensions
235x155x24 mm

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