Solution Thermodynamics and Its Application to Aqueous Solutions : A Differential Approach

Language: English

Published by Elsevier BV Nov 2007, 2007

0444530738 / 9780444530738

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Seller: AHA-BUCH GmbH, Einbeck, GermanyAHA-BUCH GmbH

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Neuware - As the title suggests, we introduce a novel differential approach to solution thermodynamics and use it for the study of aqueous solutions. We evaluate the quantities of higher order derivative than the normal thermodynamic functions. We allow these higher derivative data speak for themselves without resorting to any model system. We thus elucidate the molecular processes in solution, (referred to in this book 'mixing scheme?), to the depth equal to, if not deeper, than that gained by spectroscopic and other methods. We show that there are three composition regions in aqueous solutions of non-electrolytes, each of which has a qualitatively distinct mixing scheme. The boundary between the adjacent regions is associated with an anomaly in the third derivatives of G. The loci of the anomalies in the temperature-composition field form the line sometimes referred as 'Koga line? We then take advantage of the anomaly of a third derivative quantity of 1-propanol in the ternary aqueous solution, 1-propanol - sample species - H2O. We use its induced change as a probe of the effect of a sample species on H2O. In this way, we clarified what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. We also apply the same methodology to ions that have been ranked by the Hofmeister series. We show that the kosmotropes (salting out, or stabilizing agents) are either hydrophobes or hydration centres, and that chaotropes (salting in, or destablizing agents) are hydrophiles.…

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Title
Solution Thermodynamics and Its Application to Aqueous Solutions : A Differential Approach
Author
Yoshikata Koga
Publisher
Elsevier BV Nov 2007
Publication year
2007
Condition
Neu
Binding
Buch
Language
English
ISBN 10
0444530738
ISBN 13
9780444530738
Item weight
615 grams
Dimensions
234x156x19 mm

AHA-BUCH GmbH

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