Simultaneous Determination Of Zn And Cu

Language: English

Published by LAP LAMBERT Academic Publishing Nov 2012, 2012

3659236055 / 9783659236051

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This item is printed on demand - Print on Demand Titel. Neuware -A simple spectrophotometric method is presented for the rapid determination of Zn using diethyldithiocarbamate(DDTC) as a new spectrophotometric reagent in a acidic (0.001 M H2SO4) aq. solution. Complex formed by Cu with DDTC is more stable than Zn. The method is based on the quantitative replacement of Zn(II) with Cu(II) from its DDTC-complex and subsequent measurement of Cu(DDTC)2 at 435 nm (¿max). Therefore, simultaneous determination of both Cu and Zn has been proposed. The average molar absorptivity of the method for Zn determination was found to be 2.86 × 105 L. mol.-1 cm.-1. The reaction is instantaneous & the absorbance remains stable for over 72 h. The Sandell's sensitivity was found to 3.076 ng cm-2 of Zn. Linear calibration range was obtained of 0.02-14 µg mL-1 for Zn & 0.02-12 µg mL-1 for Cu. The stoichiometric composition of chelate is 1:2 (Zn/Cu : DDTC). The method is characterized by a detection limit of 0.29 µg mL-1 for Zn & 0.23 µg mL-1 for Cu. Large excess of over 50 cations, anions & complexing agents do not interfere in the determination. The method was successfully applied to a number of environmental, biological, food, pharmaceutical & fertilizer samples.OmniScriptum SRL, Str. Armeneasca 28/1, office 1, 2012 Chisinau 148 pp. Englisch.…

Seller Inventory # 9783659236051

Title
Simultaneous Determination Of Zn And Cu
Author
Mohammad Amzad Hossain Bhuyan
Publisher
LAP LAMBERT Academic Publishing Nov 2012
Publication year
2012
Condition
Neu
Binding
Taschenbuch
Language
English
ISBN 10
3659236055
ISBN 13
9783659236051
Item weight
238 grams
Dimensions
220x150x10 mm

buchversandmimpf2000

Emtmannsberg, BAYE, Germany

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