Reactivity of Nitric Oxide on Copper Surfaces

Language: English

Published by Springer, Springer Dez 2018, 2018

9811351740 / 9789811351747

Series: Book 285 of 797 - Springer Theses

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This item is printed on demand - Print on Demand Titel. Neuware -This book provides microscopic insights into chemical properties of NO on metal surfaces. NO/metal systems have been studied intensively to understand heterogeneous catalysis to detox exhaust NOx gas. The identification and componential analysis of various and mixed chemical species of NO adsorbed onto the surfaces have been significant challenges faced by conventional experimental techniques, such as vibrational spectroscopies. The author investigated 'individual' NO molecules on Cu surfaces using low-temperature scanning tunneling microscopy (STM). STM not only provides information on the geometric, electronic, and vibrational properties at the single-molecule level; it is also able to manipulate molecules on surfaces to induce chemical reaction. Exploiting those techniques, the author chemically identified individual NO-related species on the surfaces and discovered new reaction processes for NO reduction, which provides microscopic insights into the catalytic mechanisms. The authoralso visualized wave functions of electrons in a valence orbital of NO and demonstrated that the wave functions are modified by the formation of covalent bonding or hydrogen bonding. This is, namely, 'the visualization of quantum mechanics in real space,' which is certainly worth reading. Furthermore, the book demonstrates that direct observation of valence orbitals helps to elucidate the reactivity of molecules adsorbed onto surfaces. This innovative approach to studying molecular properties will contribute to further development of STM and its related methods.Springer-Verlag KG, Sachsenplatz 4-6, 1201 Wien 144 pp. Englisch.…

Seller Inventory # 9789811351747

Title
Reactivity of Nitric Oxide on Copper Surfaces
Author
Akitoshi Shiotari
Publisher
Springer, Springer Dez 2018
Publication year
2018
Condition
Neu
Binding
Taschenbuch
Language
English
ISBN 10
9811351740
ISBN 13
9789811351747
Item weight
230 grams
Dimensions
235x155x9 mm
Series
Book 285 of 797: Springer Theses

buchversandmimpf2000

Emtmannsberg, BAYE, Germany

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