Organometallic Compounds
Language: English
Published by Springer Netherlands, Springer Feb 2012, 2012
- Softcover
- New
Seller: BuchWeltWeit Ludwig Meier e.K., Bergisch Gladbach, GermanyBuchWeltWeit Ludwig Meier e.K.
AbeBooks seller since January 11, 2012
Condition: New
£ 47.24
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Add to basketItem description from seller
This item is printed on demand - it takes 3-4 days longer - Neuware -A very large number of organo derivatives is formed by the Group IV ele ments silicon, germanium, tin, and lead. In comparing the general properties of these elements, Table 1. 1 shows that the first ionization energies decrease (though not in a regular way) with increase in size and atomic number, con sistent with the general increase in metallic character of the elements. Electro negativity values (which have been the subject of considerable controversy) show no clear trend. Although purely inorganic compounds of tin(n) and leaden) are well known, almost all organo Group IV derivatives show an oxidation state of IV. Bonds to carbon become weaker on passing from silicon to lead, as do the element-element bonds themselves. With any particular element M (M = Si, Ge, Sn, or Pb), there is a small decrease in bond energy in the order: M-Ph M - Me M - Et. Although accurate data for organo derivatives are lacking, strengths of bonds to other elements probably decrease in the order: M-F M-O M-CI M-H ~ M-N ~ M-S ~ M-Br M-I, while for a particular element X, the order is: Si-X Ge-X Sn-X Pb-X. It is therefore understandable that reactions leading to Si-F, Si-O, or Si-CI bonds are especially favoured in a thermodynamic sense. 540 pp. Englisch.…
Seller Inventory # 9789400957312
- Title
- Organometallic Compounds
- Author
- B. J. Aylett
- Publisher
- Springer Netherlands, Springer Feb 2012
- Publication year
- 2012
- Condition
- Neu
- Binding
- Taschenbuch
- Language
- English
- ISBN 10
- 9400957319
- ISBN 13
- 9789400957312
- Item weight
- 809 grams
- Dimensions
- 235x155x29 mm
"Synopsis" may belong to another edition of this title.
BuchWeltWeit Ludwig Meier e.K.
Bergisch Gladbach, Germany
AbeBooks seller since January 11, 2012
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BuchWeltWeit Ludwig Meier e.K.
Germany
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