Magnetic Functions Beyond the Spin-Hamiltonian
Language: English
Published by Springer Berlin Heidelberg, 2006
- Hardcover
- New
Condition: New
£ 297.37
Quantity: Over 20 available
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Presents critical reviews of the present position and future trends in modern chemical research concerned with chemical structure and bondingShort and concise reports, each written by the world s renowned expertsStill valid and useful after.
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- Title
- Magnetic Functions Beyond the Spin-Hamiltonian
- Author
- Mingos, David M. P.
- Publisher
- Springer Berlin Heidelberg
- Publication year
- 2006
- Condition
- New
- Binding
- Gebunden
- Language
- English
- ISBN 10
- 354026079X
- ISBN 13
- 9783540260790
- Seller catalogs
- Mathematik/Naturwissenschaften/Technik/Medizin
Using the spin-Hamiltonian formalism the magnetic parameters are introduced through the components of the Lambda-tensor involving only the matrix elements of the angular momentum operator. The energy levels for a variety of spins are generated and the modeling of the magnetization, the magnetic susceptibility and the heat capacity is done. Theoretical formulae necessary in performing the energy level calculations for a multi-term system are prepared with the help of the irreducible tensor operator approach. The goal of the programming lies in the fact that the entire relevant matrix elements (electron repulsion, crystal field, spin-orbit interaction, orbital-Zeeman, and spin-Zeeman operators) are evaluated in the basis set of free-atom terms. The modeling of the zero-field splitting is done at three levels of sophistication. The spin-Hamiltonian formalism offers simple formulae for the magnetic parameters by evaluating the matrix elements of the angular momentum operator in the basis set of the crystal-field terms. The magnetic functions for dn complexes are modeled for a wide range of the crystal-field strengths.
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