Ligand Substitution Processes (Frontiers in Chemistry)
Published by W. A. Benjamin, 1966
- Hardcover
- Used
Condition: Used - Good
£ 11.54
Quantity: 1 available
Add to basketItem description from seller
Retired library book with usual library markings. Text free of underlining, writing and highlighting. Preface The subject of the mechanistic study of ligand substitution reactions is currently undergoing an exciting growth. New fast-reaction techniques have removed the upper limit on rates that can be measured, and extension to less familiar central metal atoms has begun in earnest. This might seem the wrong moment for review of the field. As yet, definitive treatment is possible only for those complexes involving mono-dentate ligands with cobalt(III) and platinum(II). But, because information is so extensive for these systems, it is clear that they are functioning as models from which concepts and experiments are generated for application over the fast-growing range of the subject. We believe that this is an important moment to reopen debate on fundamentals so that concepts will be most felicitously formulated to aid growth of understanding. This monograph is centrally concerned with three aspects of those fundamentals. We have attempted to develop an approach to classification of ligand substitution reactions that is adapted to what seem to have emerged as the characteristic features of these reactions and is susceptible to operational tests. (We do recognize that any such scheme of ideas is necessarily obsolescent once it is formulated since new experiments will certainly follow immediately.) We have tried to evaluate the basis for making generalizations about ligand substitution processes and to formulate tests to show whether new reactions fall within familiar patterns. Finally, we have sought to base the models of ligand substitution processes in the language of molecular-orbital theory. We believe that MO theory is most useful, because it may be used to correlate rate data on complexes with the extensive information available from spectral and magnetic studies, yet differs from crystal-field theory in providing a natural place for consideration of the bonding electrons, which must be a principal determinant of reaction processes. 111 pages.…
Seller Inventory # WB038378
Bibliographic details
- Title
- Ligand Substitution Processes (Frontiers in Chemistry)
- Author
- Cooper Harold Langford
- Publisher
- W. A. Benjamin
- Publication year
- 1966
- Condition
- Good
- Binding
- Hardcover
- Seller catalogs
- SCIENCE::Chemistry::General
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