Late Transition Metal-Carboryne Complexes : Synthesis, Structure, Bonding, and Reaction with Alkenes and Alkynes
Language: English
Published by Springer, 2014
- Softcover
- New
Seller: AHA-BUCH GmbH, Einbeck, GermanyAHA-BUCH GmbH
AbeBooks seller since August 14, 2006
Condition: New
£ 99.60
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Add to basketItem description from seller
Druck auf Anfrage Neuware - Printed after ordering - Zaozao Qiu shows in this thesis that transition metals can mediate or catalyze the cycloaddition or coupling reactions of carboryne with alkynes or alkenes to afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes. These results represent powerful strategies to assemble useful complex molecules from very simple precursors in a single operation. Carboranes have many applications in medicine. However, their unique structures make derivatization difficult and the limited efficient synthetic methods to obtain functional carborane materials have restricted applications of carboranes within a narrow scope. This work breaks a new ground in metal-carboryne chemistry and will have a significant impact on synthetic, cluster and materials chemistry.
Seller Inventory # 9783642435027
- Title
- Late Transition Metal-Carboryne Complexes : Synthesis, Structure, Bonding, and Reaction with Alkenes and Alkynes
- Author
- Zaozao Qiu
- Publisher
- Springer
- Publication year
- 2014
- Condition
- Neu
- Binding
- Taschenbuch
- Language
- English
- ISBN 10
- 3642435025
- ISBN 13
- 9783642435027
- Item weight
- 242 grams
- Dimensions
- 235x155x9 mm
"Synopsis" may belong to another edition of this title.
From the Back Cover
In this thesis, Zaozao Qiu shows that transition metals can mediate or catalyze cycloaddition and coupling reactions of carboryne with alkynes or alkenes. These reactions afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes, and are powerful strategies to assemble useful complex molecules in a single operation from very simple precursors. Carboranes have many applications in medicine. However, their unique structures make derivatization difficult and until now limited efficient synthetic methods to obtain functional carborane materials have restricted their application. This work breaks new ground in metal-carboryne chemistry and will have a significant impact on synthetic, cluster and materials chemistry.
"About the title" may belong to another edition of this title.
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