Ionic liquids, use and specific task as solvent in catalytic reaction

Language: English

Published by LAP LAMBERT Academic Publishing Sep 2010, 2010

383833406X / 9783838334066

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Seller: BuchWeltWeit Ludwig Meier e.K., Bergisch Gladbach, GermanyBuchWeltWeit Ludwig Meier e.K.

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This item is printed on demand - it takes 3-4 days longer - Neuware -Ionic liquids, associations of organic cations and anions, are media organized over several nanometers and present a segregation in polar and nonpolar microdomains. As they are used as solvents for catalytic reactions, they can induce specific solvation phenomena. For instance, ion exchange reactions in some catalytic systems and some py-cation interactions with unsaturated hydrocarbons have been observed by NMR. The consequences of the specific solvation on hydrogenation reactions have been studied. It appears that the stronger the interactions between IL and reactants are, the slower the reactions are. The presence of nonpolar and polar microdomains leads to a preferential solvation of organometallic complexes in apolar pockets that enable the use of these media as supramolecular matrices and to control the crystal growth of metal nanoparticles generated in situ according to the alkyl chain length and the temperature. 144 pp. Englisch.…

Seller Inventory # 9783838334066

Title
Ionic liquids, use and specific task as solvent in catalytic reaction
Author
Thibaut Gutel
Publisher
LAP LAMBERT Academic Publishing Sep 2010
Publication year
2010
Condition
Neu
Binding
Taschenbuch
Language
English
ISBN 10
383833406X
ISBN 13
9783838334066
Item weight
233 grams
Dimensions
220x150x9 mm

BuchWeltWeit Ludwig Meier e.K.

Bergisch Gladbach, Germany

5-star seller

AbeBooks seller since January 11, 2012

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BuchWeltWeit Ludwig Meier e.K.

Germany