Efficient Conversion of Carbohydrate Biomass to Formic Acid via Heterogeneous Catalysis

Language: English

Published by Eliva Press Sep 2025, 2025

999932424X / 9789999324243

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This item is printed on demand - Print on Demand Titel. Neuware -The conversion of biomass to chemicals/fuels has emerged as a valuable solution that offers both environmental and economic benefits, with the transformation of carbohydrate into formic acid garnering escalating scholar interest. However, the relative limited efficiency of catalyzed-oxidation or expensive cost of H2O2 and alkali in wet hydrothermal oxidation impose limitations on industrialization. This book proposed two new ideas for formic acid production by the oxidation of carbohydrate. In the first method, a two-step reaction method was developed, where the initial step is engineered to regulate the carbon chain cleavage of carbohydrates to augment the production of active intermediate. Oxygen was employed in the subsequent step as effective oxidant through free radical mechanism at around 423 K, resulting in a formic acid yield of 82.6%. Finally, the universality of the reaction was verified by using disaccharides and polysaccharides such as cellulose as substrates. In the second method, a simple but efficient MgO-H2O2 system without adding extra homogeneous base was established, achieving the highest 78.6% formic acid yield with 90.5% glucose conversion within 4 h at 323 K in water as a green medium. The catalyst MgO could be recycled five times without decline in activity with simple regeneration procedure, which occupied only 2.3% of the total operation cost based on an ex-anti life-cycle assessment, and is much cheaper than its homogenous counterpart such as LiOH. These research advance carbohydrate efficient oxidation into formic acid with heterogeneous catalyst, establishing possible approaches to produce formic acid from renewable biomass resources in real application.Libri GmbH, Europaallee 1, 36244 Bad Hersfeld 88 pp. Englisch.

Seller Inventory # 9789999324243

Title
Efficient Conversion of Carbohydrate Biomass to Formic Acid via Heterogeneous Catalysis
Author
Yang Yang
Publisher
Eliva Press Sep 2025
Publication year
2025
Condition
Neu
Binding
Taschenbuch
Language
English
ISBN 10
999932424X
ISBN 13
9789999324243
Item weight
142 grams
Dimensions
229x152x5 mm

buchversandmimpf2000

Emtmannsberg, BAYE, Germany

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