Synopsis
Ionic liquids, associations of organic cations and anions, are media organized over several nanometers and present a segregation in polar and nonpolar microdomains. As they are used as solvents for catalytic reactions, they can induce specific solvation phenomena. For instance, ion exchange reactions in some catalytic systems and some py-cation interactions with unsaturated hydrocarbons have been observed by NMR. The consequences of the specific solvation on hydrogenation reactions have been studied. It appears that the stronger the interactions between IL and reactants are, the slower the reactions are. The presence of nonpolar and polar microdomains leads to a preferential solvation of organometallic complexes in apolar pockets that enable the use of these media as supramolecular matrices and to control the crystal growth of metal nanoparticles generated in situ according to the alkyl chain length and the temperature.
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Ionic liquids, use and specific task as solvent in catalytic reaction
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LAP LAMBERT Academic Publishing Sep 2010, 2010
ISBN 10: 383833406X
ISBN 13: 9783838334066
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Taschenbuch. Condition: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -Ionic liquids, associations of organic cations and anions, are media organized over several nanometers and present a segregation in polar and nonpolar microdomains. As they are used as solvents for catalytic reactions, they can induce specific solvation phenomena. For instance, ion exchange reactions in some catalytic systems and some py-cation interactions with unsaturated hydrocarbons have been observed by NMR. The consequences of the specific solvation on hydrogenation reactions have been studied. It appears that the stronger the interactions between IL and reactants are, the slower the reactions are. The presence of nonpolar and polar microdomains leads to a preferential solvation of organometallic complexes in apolar pockets that enable the use of these media as supramolecular matrices and to control the crystal growth of metal nanoparticles generated in situ according to the alkyl chain length and the temperature. 144 pp. Englisch. Seller Inventory # 9783838334066
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Ionic liquids, use and specific task as solvent in catalytic reaction
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Ionic Liquids, Use And Specific Task As Solvent In Catalytic Reaction
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ISBN 10: 383833406X
ISBN 13: 9783838334066
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Ionic liquids, use and specific task as solvent in catalytic reaction
Published by
LAP LAMBERT Academic Publishing, 2010
ISBN 10: 383833406X
ISBN 13: 9783838334066
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Taschenbuch. Condition: Neu. nach der Bestellung gedruckt Neuware - Printed after ordering - Ionic liquids, associations of organic cations and anions, are media organized over several nanometers and present a segregation in polar and nonpolar microdomains. As they are used as solvents for catalytic reactions, they can induce specific solvation phenomena. For instance, ion exchange reactions in some catalytic systems and some py-cation interactions with unsaturated hydrocarbons have been observed by NMR. The consequences of the specific solvation on hydrogenation reactions have been studied. It appears that the stronger the interactions between IL and reactants are, the slower the reactions are. The presence of nonpolar and polar microdomains leads to a preferential solvation of organometallic complexes in apolar pockets that enable the use of these media as supramolecular matrices and to control the crystal growth of metal nanoparticles generated in situ according to the alkyl chain length and the temperature. Seller Inventory # 9783838334066
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Ionic liquids, use and specific task as solvent in catalytic reaction
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LAP LAMBERT Academic Publishing, 2010
ISBN 10: 383833406X
ISBN 13: 9783838334066
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Taschenbuch. Condition: Neu. Ionic liquids, use and specific task as solvent in catalytic reaction | Thibaut Gutel | Taschenbuch | 144 S. | Englisch | 2010 | LAP LAMBERT Academic Publishing | EAN 9783838334066 | Verantwortliche Person für die EU: preigu GmbH & Co. KG, Lengericher Landstr. 19, 49078 Osnabrück, mail[at]preigu[dot]de | Anbieter: preigu. Seller Inventory # 101369970
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Ionic liquids, use and specific task as solvent in catalytic reaction
Published by
LAP LAMBERT Academic Publishing Sep 2010, 2010
ISBN 10: 383833406X
ISBN 13: 9783838334066
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Taschenbuch
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Taschenbuch. Condition: Neu. This item is printed on demand - Print on Demand Titel. Neuware -Ionic liquids, associations of organic cations and anions, are media organized over several nanometers and present a segregation in polar and nonpolar microdomains. As they are used as solvents for catalytic reactions, they can induce specific solvation phenomena. For instance, ion exchange reactions in some catalytic systems and some py-cation interactions with unsaturated hydrocarbons have been observed by NMR. The consequences of the specific solvation on hydrogenation reactions have been studied. It appears that the stronger the interactions between IL and reactants are, the slower the reactions are. The presence of nonpolar and polar microdomains leads to a preferential solvation of organometallic complexes in apolar pockets that enable the use of these media as supramolecular matrices and to control the crystal growth of metal nanoparticles generated in situ according to the alkyl chain length and the temperature.VDM Verlag, Dudweiler Landstraße 99, 66123 Saarbrücken 144 pp. Englisch. Seller Inventory # 9783838334066