Study On Metalloporphyrins: Synthesis and characterization of new meso-substituted metalloporphyrins - Softcover
Synopsis
The work presented in the Book entitled “Study on Metalloporphyrins” can be summarized in analytical and physical data; spectral data are compatible with the suggested structures. The complexes are colored, stable in air and insoluble in H2O, ethanol and non-polar solvents such as benzene. However, they dissolve in polar solvents such as DMF and DMSO. IR spectra of the complexes were recorded to confirm their structures. The assignments of the characteristic vibrational frequencies of the complexes were made by comparison with the vibrational frequencies of the free ligand. The ligand behaved as neutral tetradentate ligand coordinating through the four imine nitrogens. In all Complexes the signals of the imine groups were merged together and shifted to lower wave number accompanied by a decrease in their intensities, indicating they are involved in complex formation. The UV–Vis absorption spectrum of the complexes shows single d–d transition band in the 554-545 nm range as expected for a square planar copper(II) environment with similar N4 donor tetradentate Schiff base. 1H NMR studies of porphyrin reveal the aromatic nature of the porphyrin macrocycle.
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About the Author
Lecturer D.K.V. Arts and Science College, Jamnagar, Gujarat (India)
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Study On Metalloporphyrins
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Scholars' Press Jun 2014, 2014
ISBN 10: 3639716507
ISBN 13: 9783639716504
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Seller: BuchWeltWeit Ludwig Meier e.K., Bergisch Gladbach, Germany
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Taschenbuch. Condition: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -The work presented in the Book entitled Study on Metalloporphyrins can be summarized in analytical and physical data; spectral data are compatible with the suggested structures. The complexes are colored, stable in air and insoluble in H2O, ethanol and non-polar solvents such as benzene. However, they dissolve in polar solvents such as DMF and DMSO. IR spectra of the complexes were recorded to confirm their structures. The assignments of the characteristic vibrational frequencies of the complexes were made by comparison with the vibrational frequencies of the free ligand. The ligand behaved as neutral tetradentate ligand coordinating through the four imine nitrogens. In all Complexes the signals of the imine groups were merged together and shifted to lower wave number accompanied by a decrease in their intensities, indicating they are involved in complex formation. The UV Vis absorption spectrum of the complexes shows single d d transition band in the 554-545 nm range as expected for a square planar copper(II) environment with similar N4 donor tetradentate Schiff base. 1H NMR studies of porphyrin reveal the aromatic nature of the porphyrin macrocycle. 60 pp. Englisch. Seller Inventory # 9783639716504
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Study On Metalloporphyrins
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VDM Verlag Dr. Mueller Aktiengesellschaft & Co. KG, 2014
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ISBN 13: 9783639716504
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Study On Metalloporphyrins
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ISBN 10: 3639716507
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Study On Metalloporphyrins
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VDM Verlag Dr. Mueller Aktiengesellschaft & Co. KG, 2014
ISBN 10: 3639716507
ISBN 13: 9783639716504
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Study On Metalloporphyrins
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Study On Metalloporphyrins
Published by
Scholars' Press Jun 2014, 2014
ISBN 10: 3639716507
ISBN 13: 9783639716504
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Taschenbuch
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Taschenbuch. Condition: Neu. This item is printed on demand - Print on Demand Titel. Neuware -The work presented in the Book entitled 'Study on Metalloporphyrins' can be summarized in analytical and physical data; spectral data are compatible with the suggested structures. The complexes are colored, stable in air and insoluble in H2O, ethanol and non-polar solvents such as benzene. However, they dissolve in polar solvents such as DMF and DMSO. IR spectra of the complexes were recorded to confirm their structures. The assignments of the characteristic vibrational frequencies of the complexes were made by comparison with the vibrational frequencies of the free ligand. The ligand behaved as neutral tetradentate ligand coordinating through the four imine nitrogens. In all Complexes the signals of the imine groups were merged together and shifted to lower wave number accompanied by a decrease in their intensities, indicating they are involved in complex formation. The UV-Vis absorption spectrum of the complexes shows single d-d transition band in the 554-545 nm range as expected for a square planar copper(II) environment with similar N4 donor tetradentate Schiff base. 1H NMR studies of porphyrin reveal the aromatic nature of the porphyrin macrocycle.VDM Verlag, Dudweiler Landstraße 99, 66123 Saarbrücken 60 pp. Englisch. Seller Inventory # 9783639716504
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Study On Metalloporphyrins : Synthesis and characterization of new meso-substituted metalloporphyrins
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Taschenbuch. Condition: Neu. nach der Bestellung gedruckt Neuware - Printed after ordering - The work presented in the Book entitled Study on Metalloporphyrins can be summarized in analytical and physical data; spectral data are compatible with the suggested structures. The complexes are colored, stable in air and insoluble in H2O, ethanol and non-polar solvents such as benzene. However, they dissolve in polar solvents such as DMF and DMSO. IR spectra of the complexes were recorded to confirm their structures. The assignments of the characteristic vibrational frequencies of the complexes were made by comparison with the vibrational frequencies of the free ligand. The ligand behaved as neutral tetradentate ligand coordinating through the four imine nitrogens. In all Complexes the signals of the imine groups were merged together and shifted to lower wave number accompanied by a decrease in their intensities, indicating they are involved in complex formation. The UV Vis absorption spectrum of the complexes shows single d d transition band in the 554-545 nm range as expected for a square planar copper(II) environment with similar N4 donor tetradentate Schiff base. 1H NMR studies of porphyrin reveal the aromatic nature of the porphyrin macrocycle. Seller Inventory # 9783639716504
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Study On Metalloporphyrins | Synthesis and characterization of new meso-substituted metalloporphyrins
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Taschenbuch. Condition: Neu. Study On Metalloporphyrins | Synthesis and characterization of new meso-substituted metalloporphyrins | Rakesh Tada (u. a.) | Taschenbuch | 60 S. | Englisch | 2014 | Scholars' Press | EAN 9783639716504 | Verantwortliche Person für die EU: preigu GmbH & Co. KG, Lengericher Landstr. 19, 49078 Osnabrück, mail[at]preigu[dot]de | Anbieter: preigu. Seller Inventory # 105199787