While books have been written on many topics of Polymer Science, no compre hensive treatise on long chain branching has ever been composed. Indeed, the most sophisticated method for analysis of long chain branching uses size exclusion fractionation with the simultaneous recording of mass, molecular weight and intrinsic visco sity of the fractions.
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The two companion volumes of Advances in Polymer Science numbers 142 and 143 deal with modern aspects of long-chain branching in synthetic polymers. The long-chain architecture is now increasingly used as a design tool for targetted polymer properties. The synthetic aspects cover branching by cationic polymerization, asymmetric branching, poly(macromonomers), dendrimer-polymer hybrids and hyperbranched polymers. Three contributions cover theory and simulation of branching, solution properties, and melt flow of branched polymers, respectively.
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