Reaction Diffusion and Solid State Chemical Kinetics: Volumes 67-68 (Materials Science Foundations, Volumes 67-68) - Softcover

Dybkov, V.I.

Softcover

ISBN 10: 0878491562 ISBN 13: 9780878491568

Publisher: Trans Tech Publications Ltd, 2010

Synopsis

Volume is indexed by Thomson Reuters BCI (WoS).
This monograph deals with a physico-chemical approach to the problem of the solid-state growth of chemical compound layers and reaction-diffusion in binary heterogeneous systems formed by two solids; as well as a solid with a liquid or a gas. It is explained why the number of compound layers growing at the interface between the original phases is usually much lower than the number of chemical compounds in the phase diagram of a given binary system. For example, of the eight intermetallic compounds which exist in the aluminium-zirconium binary system, only ZrAl3 was found to grow as a separate layer at the Al–Zr interface under isothermal conditions. The physico-chemical approach predicts that, in most cases, the number of compound layers should not exceed two; with the main factor, resulting in the appearance of additional layers, being crack formation due to thermal expansion and volume effects.

Edition details

• Publisher: Trans Tech Publications Ltd
• Publication date: 2010
• Language: English
• ISBN 10: 0878491562
• ISBN 13: 9780878491568
• Binding: Paperback
• Edition number: 2
• Number of pages: 334