Readability combines with a complete and systematic presentation of material in the sixth edition of this classic, student-oriented textbook. Simple language, new worked examples and problems, and concentrated coverage of topics in smaller units provide majors and nonmajors with a solid introduction to quantitative analytical chemistry in a one- or two- semester course. Features on biomedical, biological, and environmental topics will interest students studyting medicine, allied health, and other areas. Mathcad Computer Exercise Supplement introduces students to a powerful and versatile mathematical tool and its application to problems and computations of analytical chemistry. Many references in this paperback supplement refer to problems and examples in the textbook. Solutions Manual saves instructors time and may also be used as a student study aid.
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1. Introduction. Section I. The Tools of Analytical Chemistry. 2. Chemicals and Apparatus: Putting the Tools to Work. 3. Important Chemical Concepts: Expressing Quantities and Concentrations. 4. The Basic Approach to Chemical Equilibrium. 5. Errors in Chemical Analysis: Assessing the Quality of Results. 6. Random Errors: How Certain Can We Be? 7. Statistical Analysis: Evaluating the Data. Section II. Principles and Applications of Chemical Equilibria. 8. Gravimetric Methods of Analysis. 9. Electrolyte Effects: Activity or Concentration? 10. How Equilibrium Calculations Can Be Applied to Complex Systems. 11. Titrations: Taking Advantage of Stoichiometric Reactions. 12. Principles of Neutralization Titrations: Determining Acids, Bases, and the pH of Buffer Solutions. 13. Titrating Polyfunctional Acids and Bases. 14. Applying Neutralization Titrations. 15. Complex-Forming Titrations: Taking Advantage of Complexing Agents and Precipitating Agents. Section III. Electrochemical Methods. 16. Elements of Electrochemistry. 17. Using Electrode potentials. 18. Applying Oxidation/Reduction Titrations. 19. Potentiometry: Measuring Concentrations of Ions and Molecules. 20. A Brief Look at Some Other Electroanalytical Methods. Section IV. Spectrochemical Analysis. 21. Spectroscopic methods of Analysis: making Measurements with Light. 22. Instruments for Measuring Absorption: Is It a Photometer, a Spectrophotometer, or a Spectrometer? 23. Applying Molecular and Atomic Spectroscopic methods: Shedding More Light on the Subject. Section V. 24. An Introduction to Analytical Separations. 25. Gas-Liquid and High-Performance Liquid Chromatography. 26. Supercritical-Fluid Chromatography, Capillary Electrophoreses, and Capillary Electrochromatography. Section VI. 27. Selected Methods of Analysis. Appendix: Solubility Product Constants at 25 C. Appendix A: Acid Dissociation Constants at 25 C. Appendix B: Formation Constants of Complex Compounds at 25 C. Appendix C: Standard and Formal Electrode Potentials. Appendix D: Use of Exponential Numbers and Logarithms. Appendix E: Volumetric Calculations Using Normality and Equivalent Weight. Appendix F: Acronyms and Abbreviations of Significance in Analytical Chemistry. Appendix G: Answers to Selected Questions and Problems. Glossary. Index.
Stanley R. Crouch is professor emeritus at Michigan State University. He received his undergraduate and M.S. degrees from Stanford University and his Ph.D. in analytical chemistry from the University of Illinois. He is the recipient of the 2001 American Chemical Society Division of Analytical Chemistry Award in Chemical Instrumentation and the 1996 ACS Division of Analytical Chemistry Award for Excellence in Teaching.
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