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Weakly Interacting Molecular Pairs: Unconventional Absorbers of Radiation in the Atmosphere: 27 (NATO Science Series: IV:, 27) - Hardcover

 
9781402015953: Weakly Interacting Molecular Pairs: Unconventional Absorbers of Radiation in the Atmosphere: 27 (NATO Science Series: IV:, 27)
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The Advanced Research Workshop entitled "Weakly Interacting Molecular Pairs: Unconventional Absorbers of Radiation in the At- sphere" was held in Abbaye de Fontevraud, France, from April 29 to May 3, 2002. The meeting involved 40 researchers from 14 countries. The goal of this meeting was to address a problem that the scienti?c community is aware of for many years. Up now, however, the so- tion for this problem is far from satisfactory. Pair e?ects are called unconventional in the title of this meeting. In speci?c spectral domains and/or geophysical conditions they are recognized to play a dominant role in the absorption/emission properties of the atmosphere. Water vapor continuum absorption is among the most prominent examples. Permanently improving accuracy of both laboratory studies and ?eld observations requires better knowledge of the spectroscopic features - tributable to molecular pairs which may form at equilibrium. The Workshop was targeted both to clarify the pending questions and, as far as feasible, to trace the path to possible answers since the underlying phenomena are yet incompletely understood and since a reliable theory is often not available. On the other hand, the lack of precise laboratory data on bimolecular absorption is often precluding the construction of reliable theoretical models. Ideally, the knowledge accumulated in the course of laboratory studies should correlate with the practical demands from those who are carrying out atmospheric ?eld measurements and space observations.

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While pair effects are referred to here as unconventional, in specific spectral domains and/or geophysical conditions they play a dominant role in the absorption/emission properties of the atmosphere, water vapour continuum absorption being one of the most prominent examples. The book clarifies still open questions in this domain and seeks to trace a path to possible answers, since the underlying phenomena are often incompletely understood and a reliable theory is often unavailable. The absence of precise laboratory data on bimolecular absorption is also often a hindrance to the construction of a reliable theoretical model. The book thus describes the latest methods, theories and techniques used to study weakly interacting molecular pairs. There is also a discussion of the serious deficiencies in our understanding of bimolecular phenomena occurring in the atmosphere that will undoubtedly stimulate new laboratory and theoretical investigations. The ultimate goal of the book is to bridge the gap between laboratory experiments, sophisticated theories and field observations in the interests of atmospheric science and applications.

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