Covalent Catalysis by Enzymes - Softcover
Some years ago one of my students and I reported that the acetate kinase reaction is mediated by a phosphorylated form of the enzyme [R. S. Anthony and L. B. Spector, lBe 245, 6739 (1970)]. The reversible reaction between ATP and acetate to give acetyl phosphate and ADP had hitherto been thought to proceed by direct transfer of a phosphoryl group from A TP to acetate in a single-displacement reaction. But now it became clear that acetate kinase was one of that substantial number of enzymes whose mech anism is that of the double displacement. For some reason, I began to wonder about the possibility that all enzymes, like acetate kinase, are double displacement enzymes, and do their work by covalent catalysis. For one thing, I could not think of a single instance of an enzyme for which single displacement catalysis had been proved, and inquiries on this point among knowledgeable friends elicited the same negative response. Moreover, it was long known that the two other kinds of chemical catalysis~homo geneous and heterogeneous~occur through the intermediary formation of a covalent bond between catalyst and reactant. I began to feel confident that chemical catalysis by enzymes must happen the same way.
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- PublisherSpringer
- Publication date2011
- ISBN 10 1461256658
- ISBN 13 9781461256656
- BindingPaperback
- Number of pages276
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Book Description Taschenbuch. Condition: Neu. Druck auf Anfrage Neuware - Printed after ordering - Some years ago one of my students and I reported that the acetate kinase reaction is mediated by a phosphorylated form of the enzyme [R. S. Anthony and L. B. Spector, lBe 245, 6739 (1970)]. The reversible reaction between ATP and acetate to give acetyl phosphate and ADP had hitherto been thought to proceed by direct transfer of a phosphoryl group from A TP to acetate in a single-displacement reaction. But now it became clear that acetate kinase was one of that substantial number of enzymes whose mech anism is that of the double displacement. For some reason, I began to wonder about the possibility that all enzymes, like acetate kinase, are double displacement enzymes, and do their work by covalent catalysis. For one thing, I could not think of a single instance of an enzyme for which single displacement catalysis had been proved, and inquiries on this point among knowledgeable friends elicited the same negative response. Moreover, it was long known that the two other kinds of chemical catalysis~homo geneous and heterogeneous~occur through the intermediary formation of a covalent bond between catalyst and reactant. I began to feel confident that chemical catalysis by enzymes must happen the same way. Seller Inventory # 9781461256656
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Book Description Condition: New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. Some years ago one of my students and I reported that the acetate kinase reaction is mediated by a phosphorylated form of the enzyme [R. S. Anthony and L. B. Spector, lBe 245, 6739 (1970)]. The reversible reaction between ATP and acetate to give acetyl phos. Seller Inventory # 4188884
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Book Description Condition: New. Num Pages: 276 pages, biography. BIC Classification: PSB. Category: (G) General (US: Trade). Dimension: 235 x 155 x 15. Weight in Grams: 450. . 2011. Paperback. . . . . Books ship from the US and Ireland. Seller Inventory # V9781461256656
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Book Description Taschenbuch. Condition: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -Some years ago one of my students and I reported that the acetate kinase reaction is mediated by a phosphorylated form of the enzyme [R. S. Anthony and L. B. Spector, lBe 245, 6739 (1970)]. The reversible reaction between ATP and acetate to give acetyl phosphate and ADP had hitherto been thought to proceed by direct transfer of a phosphoryl group from A TP to acetate in a single-displacement reaction. But now it became clear that acetate kinase was one of that substantial number of enzymes whose mech anism is that of the double displacement. For some reason, I began to wonder about the possibility that all enzymes, like acetate kinase, are double displacement enzymes, and do their work by covalent catalysis. For one thing, I could not think of a single instance of an enzyme for which single displacement catalysis had been proved, and inquiries on this point among knowledgeable friends elicited the same negative response. Moreover, it was long known that the two other kinds of chemical catalysis~homo geneous and heterogeneous~occur through the intermediary formation of a covalent bond between catalyst and reactant. I began to feel confident that chemical catalysis by enzymes must happen the same way. 292 pp. Englisch. Seller Inventory # 9781461256656
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