Items related to Reactivity of Ylenes at Late Transition Metal Centers

Reactivity of Ylenes at Late Transition Metal Centers - Softcover

 
9783869559070: Reactivity of Ylenes at Late Transition Metal Centers
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  • PublisherCuvillier Verlag
  • Publication date2011
  • ISBN 10 3869559071
  • ISBN 13 9783869559070
  • BindingPaperback

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Burgert Blom
Published by Cuvillier Okt 2011 (2011)
ISBN 10: 3869559071 ISBN 13: 9783869559070
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BuchWeltWeit Ludwig Meier e.K.
(Bergisch Gladbach, Germany)

Book Description Taschenbuch. Condition: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -Heavy main group elements, i.e. those where n > 2, exhibit a marked decreasing propensity to engage in pi- bond formation compared to the lighter elements. This presents a huge challenge in contemporary inorganic chemistry and in terms of triple bonding between heavy main group elements and transition metals, reports are rare. In fact, there are only a few examples of complexes featuring triple bond formation to the heavier homologues of carbon (Si ¿ Pb), and in all these cases the transition metal is always a member of group 6 (Cr, Mo, W). This dissertation explores the general reactivity of Power-type ylenes: [EXR] (where E = Ge, Sn and Pb; X = Cl or Br; and R = a bulky m-terphenyl substituent) towards a range of late transition metal complexes in group 8, 9 and 10 with the overall goal of making triple bonds between Ge ¿ Pb with these late transition metal element atoms, hitherto unprecedented. The work described here uncovered the first examples of any transition metal beyond group 6 (Fe) engaging in a triple bond interaction to any heavy homologue of carbon. 308 pp. Englisch. Seller Inventory # 9783869559070

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Burgert Blom
Published by Cuvillier
ISBN 10: 3869559071 ISBN 13: 9783869559070
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AHA-BUCH GmbH
(Einbeck, Germany)

Book Description Taschenbuch. Condition: Neu. nach der Bestellung gedruckt Neuware - Printed after ordering - Heavy main group elements, i.e. those where n > 2, exhibit a marked decreasing propensity to engage in pi- bond formation compared to the lighter elements. This presents a huge challenge in contemporary inorganic chemistry and in terms of triple bonding between heavy main group elements and transition metals, reports are rare. In fact, there are only a few examples of complexes featuring triple bond formation to the heavier homologues of carbon (Si ¿ Pb), and in all these cases the transition metal is always a member of group 6 (Cr, Mo, W). This dissertation explores the general reactivity of Power-type ylenes: [EXR] (where E = Ge, Sn and Pb; X = Cl or Br; and R = a bulky m-terphenyl substituent) towards a range of late transition metal complexes in group 8, 9 and 10 with the overall goal of making triple bonds between Ge ¿ Pb with these late transition metal element atoms, hitherto unprecedented. The work described here uncovered the first examples of any transition metal beyond group 6 (Fe) engaging in a triple bond interaction to any heavy homologue of carbon. Seller Inventory # 9783869559070

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Blom, Burgert
Published by Jentzsch-Cuvillier, Annette (2011)
ISBN 10: 3869559071 ISBN 13: 9783869559070
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moluna
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Book Description Condition: New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. KlappentextrnrnHeavy main group elements, i.e. those where n > 2, exhibit a marked decreasing propensity to engage in pi- bond formation compared to the lighter elements. This presents a huge challenge in contemporary inorganic chemistry and in . Seller Inventory # 118877159

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