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Asymmetric Organocatalysis

Albrecht Berkessel

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ISBN 10: 3527305173 / ISBN 13: 9783527305179
Published by Wiley VCH Verlag Gmbh Jan 2005, 2005
New Condition: Neu
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Neuware - Die enantioselektive Synthese ist eine eine Herausforderung für den modernen Organiker. Die weit verbreitete enantioselektiveKatalyse mittels chiraler Metallkomplexe kann Probleme bei der Produktabtrennung verursachen. Eine elegante Alternative ist die Katalyse mittels kleiner chiraler organischer Moleküle. Das erfahrene Autorengespann aus Hochschule und Industrie gibt mit diesem Handbuch erstmals eine Übersicht über den Einsatz solcher nicht metallhaltiger Katalysatoren in der Laborpraxis.Alle wichtigen Reaktionstypen wie nucleophile Substitution, nucleophile Addition, Cycloaddition, Oxidation und Reduktion werden behandelt. Daneben werden verschiedene Verfahren zur Racemattrennung vorgestellt. Ein zusätzlicher Fokus liegt auf den industriellen Anwendungsmöglichkeiten der neuen Verfahren.Mit einer umfassenden Beschreibung der Synthesestrategien und Methoden wendet sich dieses Buch an den praktisch arbeitenden Chemiker in Industrie und Hochschule und sollte in keinem Labor fehlen. Asymmetric catalysis represents still one of the major challenges in modern organic chemistry. Besides the well-established asymmetric metal-complex-catalysed syntheses and biocatalysis, the use of 'pure' organic catalysts turned out to be an additional efficient tool for the synthesis of chiral building blocks. In this handbook, the experienced authors from academia and industry provide the first overview of the important use of such metal-free organic catalysts in organic chemistry. With its comprehensive description of numerous reaction types, e.g., nucleophilic substitution and addition reactions as well as cycloadditions and redox reactions, this book targets organic chemists working in industry and academia, and deserves a place in every laboratory. 440 pp. Englisch. Bookseller Inventory # 9783527305179

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Bibliographic Details

Title: Asymmetric Organocatalysis

Publisher: Wiley VCH Verlag Gmbh Jan 2005

Publication Date: 2005

Binding: Buch

Book Condition:Neu

About this title

Synopsis:

Asymmetric catalysis represents still one of the major challenges in modern organic chemistry. Besides the well-established asymmetric metal-complex-catalysed syntheses and biocatalysis, the use of "pure" organic catalysts turned out to be an additional efficient tool for the synthesis of chiral building blocks. In this handbook, the experienced authors from academia and industry provide the first overview of the important use of such metal-free organic catalysts in organic chemistry. With its comprehensive description of numerous reaction types, e.g., nucleophilic substitution and addition reactions as well as cycloadditions and redox reactions, this book targets organic chemists working in industry and academia, and deserves a place in every laboratory.

From the Back Cover:

Asymmetric catalysis is of ever-increasing importance in organic synthesis, both in the academic and the industrial environment. Between the extremes of metal-based and biocatalytic methods, the use of low-molecular weight and purely organic catalysts has become a third and highly efficient tool for enantioselective transformations. In this book, two experienced authors from academia and industry provide the first comprehensive overview of both the development and the current state of asymmetric organocatalysis. After a historical introduction, all synthetically relevant reaction types, such as nucleophilic substitution, addition to C=X bonds, cycloadditions and redox reactions are thoroughly discussed in a total of 11 chapters, followed by a consideration of large scale applications of organocatalysis. Additionally, the most frequently used organocatalysts and their properties are summarized in an appendix, aiding the research chemist in selecting an appropriate catalyst for a given transformation. Overall, this book targets organic chemists active both in industry and academia, and it deserves a place in every laboratory.
From the Contents:

- Introduction: Organocatalysis - From Biomimetic Concepts to Powerful Methods for Asymmetric Synthesis
- Nucleophilic Substitution at Aliphatic Carbon, e.g. Amino Acid Synthesis by Alkylation
- Nucleophilic Addition to C=C, C=N, C=O, N=N and N=O Double Bonds
- Synthesis of Epoxides and Aziridines
- Cycloaddition Reactions
- Protonation of Enolates
- Oxidation/Reduction
- Kinetic Resolution of Racemic Alcohols and Amines
- Desymmetrization of meso- and prochiral Compounds
- Large-scale Applications
- Appendix: Tabular Survey of Frequently used Organocatalysts

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