Additions to and Substitutions at C-C ?-Bonds (Comprehensive Organic Synthesis)

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9780080405957: Additions to and Substitutions at C-C ?-Bonds (Comprehensive Organic Synthesis)

Volume 4 focuses on additions and the resulting substitutions at carbon-carbon &pgr;-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient &pgr;-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to &pgr;-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.

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1993 This work is truly international, being compiled by more than 250 authors from 15 countries. The editors and publisher are to be congratulated on bringing together so many individual contributions into a cohesive work, which will be a boon to organic chemists for years to come. -- Chemistry in Australia

Essential for all industrial and academic chemistry libraries serving advanced undergraduate and graduate systems. -- H.T. McKone, Saint Joseph College, Choice

October 1992 Essential for all industrial and academic chemistry libraries serving advanced undergraduate and graduate systems. -- H.T. McKone, Saint Joseph College, Choice

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